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Total synthesis of mangiferaelactone |
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| Authors: | Paresh M Vadhadiya CV Ramana |
| Institution: | Division of Organic Chemistry, CSIR-National Chemical Laboratory, Pune 411 008, India |
| Abstract: | Herein we document the first total synthesis of mangiferaelactone and thus establish its absolute configuration. The central nonenolide ring was constructed using ring closing metathesis and Yamaguchi esterification. The key alcohol fragment was synthesized by the Bernet–Vasella fragmentation of C-ribofuranoside. |
| Keywords: | Total synthesis Nonenolide Ring closing metathesis Bernet&ndash Vasella fragmentation Yamaguchi protocol |
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