The alkaloids from the fruits of the plant Daphniphyllaceae |
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Authors: | M. Toda H. Niwa H. Irikawa Y. Hirata S. Yamamura |
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Affiliation: | Chemical Institute, Nagoya University, Chikusa-ku, Nagoya Japan;Faculty of Pharmacy, Meijo University, Showa-ku, Nagoya, Japan |
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Abstract: | Six alkaloids have been isolated from the fruits of the plant Daphniphyllaceae. Two of them are new alkaloids, namely methyl homodaphniphyllate (1) and daphnilactone-B (2). The structure of the former was deduced by chemical transformation from daphniphylline (3). The structure of daphnilactone-B was estimated by the exhaustive spectral analysis as well as by chemical evidences, and finally determined by an X-ray crystallographic analysis of the free base. |
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