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The alkaloids from the fruits of the plant Daphniphyllaceae
Authors:M. Toda  H. Niwa  H. Irikawa  Y. Hirata  S. Yamamura
Affiliation:Chemical Institute, Nagoya University, Chikusa-ku, Nagoya Japan;Faculty of Pharmacy, Meijo University, Showa-ku, Nagoya, Japan
Abstract:Six alkaloids have been isolated from the fruits of the plant Daphniphyllaceae. Two of them are new alkaloids, namely methyl homodaphniphyllate (1) and daphnilactone-B (2). The structure of the former was deduced by chemical transformation from daphniphylline (3). The structure of daphnilactone-B was estimated by the exhaustive spectral analysis as well as by chemical evidences, and finally determined by an X-ray crystallographic analysis of the free base.
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