Organic synthesis by means of noble metal complexes—XCIV : Palladium catalyzed hydrosilylation of monoenes and conjugated dienes |
| |
| Authors: | J. Tsuji M. Hara K. Ohno |
| |
| Affiliation: | Basic Research Laboratories, Toray Industries, Inc., Kamakura, Japan |
| |
| Abstract: | ![]()
Palladium compounds and metallic palladium combined with phosphine are active catalysts of selective hydrosilylation of terminal olefins. Butadiene and trichlorosilane give a 1:1 adduct and trimethylsilane affords a 1:2 adduct. Special features of the palladium catalyzed hydrosilylation reactions are presented. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
