| 2,5-噻吩齐聚物链结构的表征 |
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| 引用本文： | 曹镛,过丁,叶成,潘美. 2,5-噻吩齐聚物链结构的表征[J]. 化学学报, 1987, 45(11): 1072-1076 |
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| 作者姓名： | 曹镛 过丁 叶成 潘美 |
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| 作者单位： | 中国科学院化学研究所 |
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| 摘 要： | 本文合成、分离和纯化了一系列2,5-噻吩齐聚物(n=2-5),作为聚噻吩的模型化合物.首次系统报道了这类化合物的质谱、^1H、^1^3C核磁共振谱和红外光谱,以对其结构进行表征,所得结果与用电化学方法制备的中性聚噻吩的相应结果进行比较,表面聚噻也具有α-α'连结的结构.
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| 关 键 词： | 红外分光光度法 质谱法 碳13核磁共振谱法 高聚物表征 质子磁共振谱法 噻吩P 链结构 齐聚物 |
Characterization of a,a,-linked thiophene oligomers |
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| CAO YONG,GUO DING,YE CHENG,PAN MEI. Characterization of a,a,-linked thiophene oligomers[J]. Acta Chimica Sinica, 1987, 45(11): 1072-1076 |
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| Authors: | CAO YONG GUO DING YE CHENG PAN MEI |
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| Abstract: | The mol. structures of the title compounds (d.p. 2-5) as model compounds for polythiophene (I) were characterized by elemental anal., mass spectrometry, and UV, IR, and NMR spectroscopy. Comparison of results obtained with neutral I prepared electrochem. confirmed that I had the same a,a'-linked chain structure as that of the model compounds |
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| Keywords: | INFRARED SPECTROPHOTOMETRY MASS SPECTROGRAPHY C13 NMR SPECTROMETRY POLYMER CHARACTERIZATION PROTON MAGNETIC RESONANCE SPECTROMETRY THIOPHENE P CHAIN STRUCTURE OLIGOMER |
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