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Carbonylative Stille coupling reactions of benzyl chlorides with allyltributylstannane catalyzed by palladium nanoparticles |
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| Authors: | Jian Sun Xiujuan Feng Ziran Zhao Yoshinori Yamamoto Ming Bao |
| Affiliation: | 1. State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116023, China;2. Department of Plastic and Reconstructive Surgery, The First Hospital of Jilin University, Changchun 130021, China;3. WPI-AIMR (WPI-Advanced Institute for Materials Research), Tohoku University, Sendai 980-8577, Japan |
| Abstract: | The carbonylative Stille coupling reaction of benzyl chlorides with allyltributylstannane was successfully conducted by using palladium nanoparticles as the catalyst under phosphine ligand-free conditions. The corresponding α,β-unsaturated ketone products were obtained in good to excellent yields. |
| Keywords: | Palladium nanoparticles Carbon monoxide Carbonylative coupling |
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