Hartree-Fock perturbation theory for systems with one-particle perturbation |
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Authors: | R. Polák V. Kvasnička |
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Affiliation: | (1) Institute of Physical Chemistry and Electrochemistry, Czechosl. Acad. Sci. Prague, Máchova 7, Praha 2, Czechoslovakia |
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Abstract: | ![]() The Hartree-Fock perturbation theory for theN-electron system with a one-particle perturbation is rederived using the resolvent operator formalism. It is shown that the second-order contribution to the total energy can be expressed in a compact form using a properly defined effective one-particle operator. Relations of the Hartree-Fock perturbation theory with both the many-body theory and the regular Hartree-Fock formalism are discussed. |
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