Short metal capillary columns packed with polymer-coated fibrous materials in high-temperature gas chromatography |
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Authors: | Saito Yoshihiro Ogawa Mitsuhiro Imaizumi Motohiro Ban Kazuhiro Abe Akira Takeichi Tsutomu Wada Hiroo Jinno Kiyokatsu |
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Institution: | School of Materials Science, Toyohashi University of Technology, Toyohashi 441-8580, Japan. |
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Abstract: | The high-temperature gas chromatographic (GC) separation of several semivolatile compounds is studied with a short metal capillary column packed with fibrous material, having a polydimethylsiloxane coating thereon. Taking advantage of the excellent heat-resistance of the fiber and also the combination of the surface-deactivated metal capillary, a temperature-programmed separation up to 450 degrees C is successfully demonstrated for the separation of polymer standard samples. The average molecular weight of the commercially-available polymer standard samples for size exclusion chromatography (SEC) is estimated by high-temperature GC analysis and compared with the nominal value determined by a conventional SEC method. Although a slight deviation for the number-average molecular weight is observed between the GC and SEC analysis, the data for the weight-average molecular weight shows a good agreement in these methods. The results also suggest the future possibility of the fiber-packed metal capillary as a miniaturized GC column with an increased sample loading capacity. |
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