Catalytic oxidation of α-pinene with tert-butyl hydroperoxide in the presence of Fe-pillared montmorillonite |
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| Authors: | E. P. Romanenko E. A. Taraban A. V. Tkachev |
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| Affiliation: | (1) N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 9 prosp. Akad. Lavrent’eva, 630090 Novosibirsk, Russian Federation;(2) G. K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, 5 prosp. Akad. Lavrent’eva, 630090 Novosibirsk, Russian Federation |
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| Abstract: | The reaction of α-pinene with tert-butyl hydroperoxide can proceed via allylic oxidation or α-pinene isomerization, depending on the structural features of the catalysts based on Fe-pillared montmorillonite. Dedicated to the memory of Academician V. A. Koptyug on the occasion of the 75th anniversary of his birth. Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 956–961, June, 2006. |
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| Keywords: | α -pinene allylic oxidation Fe-pillared montmorillonite mechanochemical activation terpenoids tert-butyl hydroperoxide 27Al NMR spectroscopy |
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