Absorption spectrum of Mn2+ ions doped in diammonium hexaaquamagnesium(II) sulfate

Optical absorption is a tool to investigate the site symmetry of metal ion and associated distortion in doped single crystals. It provides the energy of different orbital levels of metal ion and separation among them. Mn²⁺ ions in various single crystals and glasses have been the subject of recent investigations [1–3]. We have studied optical absorption spectra of Mn²⁺ doped diammonium hexaaquamagnesium(II) sulfate in order to obtain the energy level ordering using matrices of Tanabe and Sugano [4] and to discuss the associated distortion.