A chromium catalyst for the polymerization of ethylene as a homogeneous model for the phillips catalyst |
| |
| Authors: | MacAdams Leonard A Buffone Gerald P Incarvito Christopher D Rheingold Arnold L Theopold Klaus H |
| |
| Institution: | Center for Catalytic Science and Technology, Department of Chemistry and Biochemistry, University of Delaware, Newark, Delaware 19716, USA. |
| |
| Abstract: | A structurally characterized cationic chromium(III) alkyl featuring a bulky nacnac ligand catalyzes the polymerization of ethylene as well as the copolymerization of ethylene with alpha-olefins. This well-characterized homogeneous catalyst constitutes a structural as well as functional model of the widely used heterogeneous Phillips olefin polymerization catalyst. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
