| 新型N-甲基-N-烯丙基吗啡啉季铵盐类离子液体的合成 |
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| 引用本文： | 张青山,刘爱霞,郭炳南,吴锋.新型N-甲基-N-烯丙基吗啡啉季铵盐类离子液体的合成[J].高等学校化学学报,2005,26(2):340-342. |
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| 作者姓名： | 张青山 刘爱霞 郭炳南 吴锋 |
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| 作者单位： | 北京理工大学化工与环境学院, 北京 100081 |
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| 基金项目： | 国家重点基础研究发展计划(973计划) |
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| 摘 要： | 离子液体对某些无机和有机物溶解性能好、液态温度和电化学窗口范围宽、热稳定性高、易制备，因而近年来成为国内外研究的热点，目前的离子液体大多由烷基吡啶或双烷基咪唑季铵盐阳离子与氯铝酸根、氟硼酸根、六氟磷酸根以及其它大的阴离子构成，在季铵盐类离子液体中，
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| 关 键 词： | 离子液体 N-甲基-N-烯丙基吗啡啉季铵盐 功能化离子液体 |
| 文章编号： | 0251-0790(2005)02-0340-03 |
| 收稿时间： | 2004-04-09 |
Synthesis of Ionic Liquids Based on the N-Methyl-N-allyl Morpholinium Cation |
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| ZHANG Qing-Shan,LIU Ai-Xia,GUO Bing-Nan,WU Feng.Synthesis of Ionic Liquids Based on the N-Methyl-N-allyl Morpholinium Cation[J].Chemical Research In Chinese Universities,2005,26(2):340-342. |
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| Authors: | ZHANG Qing-Shan LIU Ai-Xia GUO Bing-Nan WU Feng |
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| Institution: | School of Chemical Engineering and the Environment, Beijing Institute of Technology, Beijing 100081, China |
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| Abstract: | The preparation of a new family of ionic liquids via the reaction between N-methyl-N-allyl- morpholinium cations was reported for the first time, and BF-_4, PF-_6 and (CF_3SO_2)_2N- bis(trifluoromethanesufonyl)imide, TFSI-]. The cation has an ether bond and is functionalized by allyl . The structure of these compounds were determined by 1H NMR and elemental analysis. Some properties were also presented in this paper. |
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| Keywords: | Ionic liquids N-Methyl-N-allyl-morpholinium salt Functionalized ionic liquids |
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