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Flash vacuum thermolysis of 1,5-Bis-(1-chloroethenyl)anthracene. The thermal conversion of cyclopent[hi]aceanthrylene into cyclopent[hi]acephenanthrylene |
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| Authors: | Martin Sarobe Judith D Snoeijer Leonardus W Jenneskens Jan W Zwikker Jolanda Wesseling |
| Institution: | Debye Institute, Department of Physical Organic Chemistry, Utrecht University, Padualaan 8, 3584 CH Utrecht, The Netherlands |
| Abstract: | Flash Vacuum Thermolysis of 1,5-bis-(1-chloroethenyl)anthracene (6) gives cyclopenthi]-aceanthrylene (2) which at T≥9000 °C rearranges to cyclopenthi]acephenanthrylene (1). This conversion occurs more readily than that of the monocyclopenta-fused aceanthrylene to acephenanthrylene. |
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