Synthese, structure cristalline et spectres infrarouges de l''acide β-alanyl amino methyl phosphonique |
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Authors: | M. Cotrait E. Dupart J. Prigent C. Garrigou-Lagrange |
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Affiliation: | Centre de Recherche Paul Pascal, Université de Bordeaux I, Domaine Universitaire, 33405 Talence Cedex France |
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Abstract: | β-Alanyl aminomethylphosphonic acid (β-ala AMPh) has been studied in the solid state by X-ray diffraction and vibration spectrometry. It crystallizes (space group P1&;#x0304; with Z = 4) as a zwitterion with, in the asymétrie unit, two independent molecules the conformations of which are quite different. The hydrogen bonding network is very complicated. Because the infrared spectra are very complicated, only a partial correlation of the vibrations of ammonium, amide and phosphonic groups is proposed. |
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