The Synthesis of Novel Crown Ethers. Part IV. Coumarin Derivatives of [18]crown-6 and Cation Binding from Fluorescence Spectra |
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Authors: | Çakil Erk Ayten Göçmen Mustafa Bulut |
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Institution: | (1) Department of Chemistry, Technical University of Istanbul, Maslak, 80626 Istanbul, Turkey |
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Abstract: | 4-H, 4-methyl and 4-phenyl-1-benzopyran-2-one derivatives of 18]crown-6 derivatives were synthesised from 6,7- and 7,8-dihydroxy-1-benzopyran-2-one reacting with pentaethylene glycol ditosylate in K2CO3/DMF/water. The products were identified by elemental analysis, EI-GC-mass spectra and 1H-NMR spectroscopy. The Na+ association constants of some coumarin derivatives were determined with an ion selective electrode in water. The Na+ , K+, Ba2+ and Sr2+ binding role of such compounds were particularly observed as remarkable alterations in acetonitrile. The 1 : 1 associations constants of K+ and Na+ with some coumarin-18]crown-6 derivatives estimated by this way in acetonitrile exhibited the utility of complexing enhanced quenching fluorescence spectra for the ion binding power of the such macrocycles. |
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Keywords: | macrocyclic ethers coumarins cation binding fluorescence spectroscopy |
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