| 铜配位聚合物[Cu(C5H6S5)(SCN)]∞的合成和结构研究(英) |
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| 引用本文： | 方国苏,纪 勇,王 石,左景林,白俊峰,游效曾.铜配位聚合物[Cu(C5H6S5)(SCN)]∞的合成和结构研究(英)[J].无机化学学报,2004,20(5):603-607. |
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| 作者姓名： | 方国苏 纪 勇 王 石 左景林 白俊峰 游效曾 |
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| 作者单位： | 南京大学配位化学研究所、配位化学国家重点实验室,南京,210093 |
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| 基金项目： | 国家自然科学基金资助项目(No.NSF20201006,90101028)。 |
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| 摘 要： | The Copper(Ⅰ) supramolecular complexes of 4,5-bis(methylthio)-1,3-dithiole-2-thione (C5H6S5), Cu(C5H6S5)(SCN)]∞ 1 and Cu(C5H6S5)I]∞ 2, have been prepared and characterized. X-ray structure analysis for complex 1 reveals that the infinite chain structure with polymeric stairs of different lengths is formed through the coordination mode (μ3) of the thiocyanate bridges. The shorter interchain S…S contacts give rise to a three-dimensional network structure. CCDC: 215668.
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| 关 键 词： | 铜配合物 晶体结构 配位聚合物 超分子 多硫配合物 |
Synthesis and Crystal Structure of a Copper(Ⅰ) Coordination Polymer with 4,5-bis(methylthio)-1,3-dithiole-2-thione Ligand |
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| FANG Guo-Su,JI Yong,WANG Shi,ZUO Jing-Lin,BAI Jun-Feng and YOU Xiao-Zeng.Synthesis and Crystal Structure of a Copper(Ⅰ) Coordination Polymer with 4,5-bis(methylthio)-1,3-dithiole-2-thione Ligand[J].Chinese Journal of Inorganic Chemistry,2004,20(5):603-607. |
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| Authors: | FANG Guo-Su JI Yong WANG Shi ZUO Jing-Lin BAI Jun-Feng and YOU Xiao-Zeng |
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| Institution: | Coordination Chemistry Institute and the State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093,Coordination Chemistry Institute and the State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093,Coordination Chemistry Institute and the State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093,Coordination Chemistry Institute and the State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093,Coordination Chemistry Institute and the State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093 and Coordination Chemistry Institute and the State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093 |
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| Abstract: | The Copper(Ⅰ) supramolecular complexes of 4,5-bis (methylthio)-1,3-dithiole-2-thione (C5H6S5), Cu (C5H6S5)
(SCN)]∞ 1 and Cu(C5H6S5)I]∞ 2, have been prepared and characterized. X-ray structure analysis for complex 1 re
veals that the infinite chain structure with polymeric stairs of different lengths is formed through the coordination mode (μ3) of the thiocyanate bridges. The shorter interchain S…S contacts give rise to a three-dimensional network structure. CCDC: 215668. |
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| Keywords: | copper complexes crystal structures polymeric complexes supramolecular complexes thione complexes |
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