The first high oxidation state manganese-calcium cluster: relevance to the water oxidizing complex of photosynthesis |
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| Authors: | Mishra Abhudaya Wernsdorfer Wolfgang Abboud Khalil A Christou George |
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| Institution: | Department of Chemistry, University of Florida, Gainesville, Florida 32611-7200, USA. |
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| Abstract: | Synthetic entry has been achieved into high oxidation state Mn-Ca cluster chemistry with the preparation of Mn(13)Ca(2)O(10)(OH)(2)(OMe)(2)(O(2)CPh)(18)(H(2)O)(4)]; the structure contains Mn(4)CaO(4)] sub-units similar to that found in the photosynthetic water oxidizing complex. |
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