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Paramagnetic triangular rhenium sulfide cluster [Re3S4(Dppe)3(NCS)3]Br |
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| Authors: | P A Petrov M Yu Afonin D Yu Naumov A S Bogomyakov S N Konchenko |
| Institution: | 1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090, Russia 2. International Tomography Center, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia |
| Abstract: | A new cluster Re3S4(Dppe)3(NCS)3]Br (Dppe = Ph2PCH2CH2PPh2) is synthesized. The molecular and crystal structures of the cluster are determined by X-ray diffraction analysis. The magnetochemical data indicate the high-spin ground state (S = 3/2) of the cluster at room temperature. |
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