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Valence shell photoionization spectra of some substituted hydroxy-acetylenes. A tentative correlation with their cyclotrimerization reactions
Authors:M.V. Andreocci  P. Bitchev  P. Carusi  A. Furlani
Affiliation:Institute of General and Inorganic Chemistry, University of Rome, Rome Italy
Abstract:
He(I) photoelectron spectra of a series of oxyacetylenes have been studied. The πCC and oxygen “lone pair” IE's have been tentatively related to the chemical behaviour of these compounds. CNDO/2 calculations have been carried out on the three simplest molecules of the series.
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