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A Triptycene-Based Porous Organic Polymer that Exhibited High Hydrogen and Carbon Dioxide Storage Capacities and Excellent CO2/N2 Selectivity |
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| Authors: | Xi-Long Lu Tian-You Zhou Doufeng Wu Qiang Wen Xin Zhao Qiaowei Li Qun Xiang |
| Affiliation: | 1. Department of Chemistry, Shanghai University, Shanghai 200444, China 2. Key Laboratory of Synthetic and Self-Assembly Chemistry for Organic Functional Molecules, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China 3. Department of Chemistry, Fudan University, Shanghai 200433, China |
| Abstract: | A novel porous organic polymer (POP) has been constructed through the condensation of triptycene tricatechol and 1,3,5‐benzenetris(4‐phenylboronic acid). This triptycene‐based POP exhibited high H2 uptake (up to 1.84 wt% at 77 K, 1 bar), large CO2 adsorption capacity (up to 18.1 wt% at 273K, 1 bar), and excellent CO2/N2 adsorption selectivity (up to 120/1). The influence of solvent on the gas adsorption performance of the POP has also been investigated. |
| Keywords: | porous organic polymers H2/CO2 adsorption CO2/N2 selectivity |