|
|||||
|
|
Preferential solvation effects in the electrochemistry and charge-transfer spectra of cyanoiron(II) complexes |
|
| Authors: | Henrique E. Toma Maria S. Takasugi |
| Affiliation: | (1) Instituto de Quimica, Universidade de Sao Paulo, CP 20780, Sao Paulo, SP, Brazil;(2) Departamento de Quimica, Univ. Federal do Parana, CP 1963, Curitiba, PR, Brazil |
| Abstract: | The energies of the charge-transfer bands and the redox potentials of substituted cyanoiron complexes are strongly influenced by preferential solvation effects in water-acetonitrile mixed solvents, exhibiting a linear dependence with respect to the acceptor number scale. The dependence increases with the number of cyanide ligands in the complexes. |
| Keywords: | Preferential solvation solvatochromism of cyanoferrates electrochemistry in mixed solvents water-acetonitrile mixtures acceptor number |
| 本文献已被 SpringerLink 等数据库收录！ | |