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solid-state reaction of a lead tetraacetate-metal halide system with naphthalene under mechanical activation
Authors:G I Nikishin  L L Sokova  V D Makhaev  L A Petrova  A V Ignatenko  N I Kapustina
Institution:1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation
2. Institute of New Chemical Problems, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation
Abstract:A mechanically activated solid-state reaction of halogenation of naphthalene with a Pb(OAc)4—alkaline or alkaline-earth metal halide system was carried out to yield 1-halonaphthalene as the main reaction product and 1,4-dihalonaphthalene. The solid-state halogenation of naphthalene is more selective than a liquid-phase reaction.
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