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Combination of spontaneous polarization plasma and photocatalyst for toluene oxidation
Institution:1. School of Environmental Science and Engineering, Nanjing University of Information Science & Technology, Nanjing 210004, China;2. Department of Environment Engineering, Nanjing Institute of Technology, Nanjing 211167, China;3. Department of Energy Technology, Royal Institute of Technology (KTH), S-10044 Stockholm, Sweden;1. School of Resource and Environmental Engineering, East China University of Science and Technology, Shanghai 200237, China;2. Clean Energy Automotive Engineering Center, Tongji University, Shanghai 201804, China;3. School of Automotive Studies, Tongji University, Shanghai 201804, China;1. Institute of Physics, Hebei Advanced Thin Films Laboratory, Hebei Normal University, Shijiazhuang 050024, China;2. Department of Mathematics and Physics, Shijiazhuang Tiedao University, Shijiazhuang 050043, China;1. State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization, Kunming University of Science and Technology, Kunming 650093, Yunnan, China;2. Faculty of Metallurgy and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, Yunnan, China
Abstract:In this paper, we report toluene destruction using a spontaneous polarization plasma and photocatalyst reactor in air at atmospheric pressure and room temperature. A spontaneous polarization material (BaTiO3) and photocatalyst (TiO2) were added to the plasma system simultaneously. Three types of catalyst, i.e., TiO2, BaTiO3, or TiO2/BaTiO3, were used for toluene removal. The catalyst carrier, type, and amount were important factors in the toluene removal efficiency. The specific energy density and energy yield during the discharge process were investigated. The toluene removal efficiency increased when a spontaneous polarization plasma was combined with the photocatalyst. In terms of toluene removal efficiency, the activity order was TiO2/BaTiO3 > BaTiO3 > TiO2 > none. Large amounts of BaTiO3 in the TiO2/BaTiO3 catalyst gave slightly better conversion. The TiO2/BaTiO3 catalyst not only enhanced the toluene removal efficiency, but also saved energy, making it useful for industrial applications.
Keywords:Spontaneous polarization plasma  Photocatalyst  Specific energy density  Toluene
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