An enantioselective fluorescent sensor for sugar acids |
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| Authors: | Zhao Jianzhang Davidson Matthew G Mahon Mary F Kociok-Köhn Gabriele James Tony D |
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| Affiliation: | Department of Chemistry and Bath Chemical Crystallography, University of Bath, Bath BA2 7AY, UK. |
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| Abstract: | Chiral fluorescent boronic acid 1 was found to be a highly enantioselective, chemoselective, and sensitive sensor for sugar acids, such as tartaric acid. Enantioselectivities (K(R)/K(S)) of up to 550:1, chemoselectivity up to 11,000:1, and sensitivities in the micromolar range with sensor 1 were observed. Single-crystal X-ray analysis was used to confirm the structure of the fluorescent species. |
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