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Reprint of: Recent advances in the functionalization of allenes via radical process |
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| Authors: | Guanyinsheng Qiu Jun Zhang Kaida Zhou Jie Wu |
| Affiliation: | 1. College of Biological, Chemical Science and Engineering, Jiaxing University, 118 Jiahang Road, Jiaxing 314001, China;2. Department of Chemistry, Fudan University, 2005 Songhu Road, Shanghai 200438, China;3. State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, China |
| Abstract: | This review is focused on the recent advances in the functionalization of allenes via radical process. Different radical partners including carbon radicals and heteroatom radicals are discussed in the reactions of allenes. Generally, the radical formed in situ would attack the allene at the central carbon leading to allyl radical intermediate. However, the formation of alkenyl radical intermediate from allene could be observed as well in some cases with high regioselectivity and stereoselectivity. |
| Keywords: | Allene Heteroatom radical Carbon radical Regioselectivity Stereoselectivity |
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