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The first total synthesis of the 6-hydroxy-4E-sphingenines |
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| Authors: | JS Yadav V GeethaA Krishnam Raju D GnaneshwarS Chandrasekhar |
| Institution: | Organic Chemistry Division I, Indian Institute of Chemical Technology, Hyderabad 500 007, India |
| Abstract: | Ceramides containing the 6-hydroxy-4E-sphingenines, previously unknown long-chain bases, have recently been found in human skin. A total synthesis of 6-hydroxy-4E-sphingenines has been achieved. |
| Keywords: | sphingolipids 6-hydroxy-4E-sphingenines Sharpless asymmetric epoxidation Garner aldehyde |
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