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Uncommon intramolecular palladium-catalyzed cyclization of indole derivatives |
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| Authors: | Egle M. Beccalli Gianluigi Broggini |
| Affiliation: | a Istituto di Chimica Organica, Università degli Studi di Milano, via Venezian 21, 20133 Milano, Italy b Dipartimento di Scienze Chimiche, Fisiche e Matematiche dell'Università dell'Insubria, via Lucini 3, 22100 Como, Italy |
| Abstract: | A novel synthetic strategy based on the intramolecular palladium-catalyzed oxidative cyclization reaction, allows the formation of C-C bond and the synthesis of β-carbolinones. The reaction has been performed in the presence of catalytic amount of PdCl2(CH3CN)2 and benzoquinone as a reoxidant. |
| Keywords: | Pd catalyst intramolecular cyclization indoles carbolinones |
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