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First total synthesis of valeriananoid A |
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| Authors: | Hisahiro Hagiwara Akihiro MoriiYu Yamada Takashi HoshiToshio Suzuki |
| Affiliation: | a Graduate School of Science and Technology, Niigata University, 8050, 2-nocho, Ikarashi, Niigata 950-2181, Japan b Department of Chemistry and Chemical Engineering, Faculty of Engineering, Niigata University, 8050, 2-nocho, Ikarashi, Niigata 950-2181, Japan |
| Abstract: | A tricyclic sesquiterpenoid, valeriananoid A 1, has been synthesized via domino Michael reaction of oxophorone 4 and subsequent 6-endo-trig cyclization of a ketyl radical as key steps. |
| Keywords: | bicyclic aliphatic compounds domino Michael reactions sesquiterpenenoid valeriananoid |
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