Palladium-catalyzed cycloreductions of haloene-ynes in the presence of triethylsilane |
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| Authors: | Chang Ho Oh Su Jin Park |
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| Institution: | Department of Chemistry, Hanyang University, Sungdong-Gu, Seoul 133-791, Republic of Korea |
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| Abstract: | Haloene-ynes 1 with a palladium catalyst would form the alkenylpalladium intermediates via intramolecular Heck reactions, which were reductively cleaved with triethylsilane or formate ligand to give the cycloreduction products 3 in good to excellent yields. |
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