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Room temperature ionic liquid promoted synthesis of 1,5-benzodiazepine derivatives under ambient conditions
Authors:D.V JarikoteS.A Siddiqui  R RajagopalThomas Daniel  R.J LahotiK.V Srinivasan
Affiliation:Division of Organic Chemistry; Technology, National Chemical Laboratory, Dr. Homi Bhabha Road, Pune 411 008, India
Abstract:The reaction of o-phenylenediamines with both acyclic and cyclic ketones in the ionic liquid 1,3-di-n-butylimidazolium bromide afforded 1,5-benzodiazepines in excellent isolated yields in the absence of a catalyst at ambient temperature.
Keywords:benzodiazepines   ionic liquid   o-phenylenediamines   green solvent
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