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Chemoselective thioacetalization and transthioacetalization of carbonyl compounds catalyzed by immobilized scandium(III) triflate in ionic liquids
Authors:Ahmed Kamal  Gagan Chouhan
Institution:Division of Organic Chemistry, Indian Institute of Chemical Technology, Hyderabad 500007, India
Abstract:Immobilized scandium triflate Sc(OTf)3] in ionic liquids has been found to be an extremely efficient and recyclable catalyst for the thioacetalization and transthioacetalization of both aromatic and aliphatic aldehydes. Significant rate acceleration and chemoselectivity was achieved by employing this catalytic system.
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