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cis-Enhanced cyclopropanation catalysts: reaction chemistry of three isomers of Rh2[N(C6H5)COCH3]4 |
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| Authors: | Cassandra T Eagle David FarrarGrant N Holder Michelle L HatleyShirley L Humphrey Elizabeth V OlsonMaria Quintos Joseph SadighiTom Wideman |
| Institution: | A. R. Smith Department of Chemistry, Appalachian State University, Boone, NC 28608, USA |
| Abstract: | The catalytic activities of three structural isomers of Rh2N(C6H5)COCH3]4 in cyclopropanation reactions were surveyed. These studies showed cis cyclopropanation selectivity with bulky alkenes for 2,2-cis- and 2,2-trans-Rh2N(C6H5)COCH3]4. |
| Keywords: | cyclopropanation rhodium catalysts catalysis rhodium carboxamides carbene |
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