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A new pathway for the preparation of diaryl acetylenes
Authors:Edgars Abele  Ramona AbelePavel Arsenyan  Edmunds Lukevics
Institution:Latvian Institute of Organic Synthesis, 21 Aizkraukles Street, Riga LV-1006, Latvia
Abstract:A simple method for the preparation of diaryl acetylenes in yields up to 61% from aryl bromides and 1-bromo-2-chloroethane using the palladium catalyst (dppb)Pd(OAc)2 under PTC conditions (solid KOH/18-crown-6) has been developed.
Keywords:acetylene  aryl bromides  palladium catalysis  phase transfer catalysis
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