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Hole transfer in DNA: DNA as a scaffold for hole transfer between two organic molecules
Authors:Tadao TakadaKiyohiko Kawai  Sachiko TojoTetsuro Majima
Institution:The Institute of Scientific and Industrial Research (SANKEN), Osaka University, Mihogaoka 8-1, Ibaraki, Osaka 567-0047, Japan
Abstract:Hole transfer process in ODNs conjugated with two organic molecules, pyrene (Py) and phenothiazine (Ptz) was investigated with the pulse radiolysis measurements. Monitoring the transient absorption of Pyradical dot+ and Ptzradical dot+, it was shown that the hole transfer rate was dependent on the distance and sequence between Py and Ptz.
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