Shape-persistent cyclyne-type azamacrocycles: synthesis, unusual light-emitting characteristics, and specific recognition of the Sb(V) ion |
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| Authors: | Shigeya KobayashiYoshihiro Yamaguchi Tateaki WakamiyaYoshio Matsubara Kunihisa SugimotoZen-ichi Yoshida |
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| Institution: | a Faculty of Science and Engineering, Kinki University, 3-4-1 Kowakae, Higashi-Osaka 577-8502, Japan
b X-Ray Research Laboratory, Rigaku Corporation, 3-9-12 Matsubara, Akishima, Tokyo 196-8666, Japan |
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| Abstract: | Simple members of arene-azaarenecyclynes as a novel family of geometrically-controlled and shape-persistent azamacrocycles have been synthesized. Noteworthy is the specific recognition function for Sb(V). The synthesized azamacrocycles, in particular the Sb(V) complex, have unusually strong light-emitting property. |
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| Keywords: | azamacrocycles antimony pentachloride coupling reaction molecular recognition |
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