| STUDIES ON SYNTHESES OF MoFe_3S_4 CUBANE-LIKE CLUSTER COMPOUNDS |
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| 引用本文： | 刘秋田,康北笙,陈昌能,黄梁仁,蔡进华,庄伯涛,卢嘉锡. STUDIES ON SYNTHESES OF MoFe_3S_4 CUBANE-LIKE CLUSTER COMPOUNDS[J]. 中国科学B辑(英文版), 1989, 0(4) |
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| 作者姓名： | 刘秋田 康北笙 陈昌能 黄梁仁 蔡进华 庄伯涛 卢嘉锡 |
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| 作者单位： | Fufian Institute of Research on-the Structure of Matter，Academia Sinica，Fuzhou，Fufian Institute of Research on-the Structure of Matter，Academia Sinica，Fuzhou，Fufian Institute of Research on-the Structure of Matter，Academia Sinica，Fuzhou，Fufian Institute of Research on-the Structure of Matter，Academia Sinica，Fuzhou，Fufian Institute of Research on-the Structure of Matter，Academia Sinica，Fuzhou，Fufian Institute of Research on-the Structure of Matter，Academia Sinica，Fuzhou，Fufian Institute of Research on-the Structure of Matter，Academia Sinica，Fuzhou |
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| 基金项目： | This work was supported by the SFAS |
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| 摘 要： | The features of synthetic processes are described on the basis of the studies of the syntheses of MoFe_3S_4 cubane-like cluster compounds either by self-assembly reactions or by the conversion of linear clusters. The redox properties and the structure of ligands as well as the stoichiometry of reactants have obvious effects upon the core oxidation state and the structure of products. It is indicated that the self-assembly reaction may pass through a combination process oflinear cluster intermediates having structural unit (M,M'=Mo) Fe).
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STUDIES ON SYNTHESES OF MoFe_3S_4 CUBANE-LIKE CLUSTER COMPOUNDS |
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| LIU QIU-TIAN KANG BEI-SHENG CHEN CHANG-NENG HUANG LIANG=REN CAI JIN-HUA ZHUANG BO-TAO LU JIA-XI. STUDIES ON SYNTHESES OF MoFe_3S_4 CUBANE-LIKE CLUSTER COMPOUNDS[J]. Science in China(Chemistry), 1989, 0(4) |
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| Authors: | LIU QIU-TIAN KANG BEI-SHENG CHEN CHANG-NENG HUANG LIANG=REN CAI JIN-HUA ZHUANG BO-TAO LU JIA-XI |
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| Abstract: | The features of synthetic processes are described on the basis of the studies of the syntheses of MoFe_3S_4 cubane-like cluster compounds either by self-assembly reactions or by the conversion of linear clusters. The redox properties and the structure of ligands as well as the stoichiometry of reactants have obvious effects upon the core oxidation state and the structure of products. It is indicated that the self-assembly reaction may pass through a combination process oflinear cluster intermediates having structural unit (M,M'=Mo) Fe). |
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| Keywords: | Mo cluster Fe clusters MoFeS clusters heterometallic thiocubane. |
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