| Synthesis and Crystal Structure of Complex [Cdq3] [Cd（qH）3]（ClO4）CH3OH（q = 8-Quinolinolate, qH = 8-Quilinolinol） |
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| 引用本文： | SHI Jing-Min② ZHANG Xia LU Jian-Jun CHEN Yu-Qin MA Jian-Ping LIU Lian-Dong.Synthesis and Crystal Structure of Complex [Cdq3] [Cd（qH）3]（ClO4）CH3OH（q = 8-Quinolinolate, qH = 8-Quilinolinol）[J].结构化学,2005,24(8):913-916. |
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| 作者姓名： | SHI Jing-Min② ZHANG Xia LU Jian-Jun CHEN Yu-Qin MA Jian-Ping LIU Lian-Dong |
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| 作者单位： | Department of Chemistry，Shandong Normal University，Jinan 250014，China |
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| 基金项目： | This work was supported by the National Natural Science Foundation of China (No. 20271043) and Natural Science Foundation of Shandong Province (No. Y2002B10) |
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| 摘 要： | 1 INTRODUCTION 8-Quinolinolate is a very useful ligand and used to synthesize many complexes with special physical properties. For example, the complex tris(8-quinoli- nolate)aluminum(III) displays distinguished physical property in the area of electroluminescence ma- terials1]. Based on tris(8-quinolinolate)aluminum(III), high-luminance low-voltage driven devices have been made, which opens the route to design low-cost large area displays and illuminators. The crystals thatcontain com…
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| 关 键 词： | 合成 晶体结构 8-喹啉醇 镉配合物 |
Synthesis and Crystal Structure of Complex [Cdq3][Cd(qH)3](ClO4)CH3OH(q = 8-Quinolinolate, qH = 8-Quilinolinol) |
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| SHI Jing-min,ZHANG Xia,LU Jian-jun,CHEN Yu-qin,MA Jian-ping,LIU Lian-dong.Synthesis and Crystal Structure of Complex [Cdq3][Cd(qH)3](ClO4)CH3OH(q = 8-Quinolinolate, qH = 8-Quilinolinol)[J].Chinese Journal of Structural Chemistry,2005,24(8):913-916. |
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| Authors: | SHI Jing-min ZHANG Xia LU Jian-jun CHEN Yu-qin MA Jian-ping LIU Lian-dong |
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| Institution: | Department of Chemistry,Shandong Normal University,Jinan 250014,China |
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| Abstract: | The mono-nuclear complex Cdq3]Cd(qH)3](ClO4)CH3OH has been synthesized by 8-quinolinol and hydrated cadmium perchlorate in methanol solution.The crystal belongs to = 88.497(2), γ= 75.681(2)°, V = 2534.1(6)(。A)3, Z = 1, C11oH86Cd4Cl2 N12O22, Mr = 2448.41, Dc =1.604 g/cm3, F(000) = 1232 andμ = 0.961 mm-1.The structure was refined to R = 0.0387 and wR =0.0973 for 7775 observed reflections (I ＞ 2σ(I)).In this crystal there exist two independent mononuclear complexes of Cdq3] and Cd(qH)3]2+.Each cell contains two Cdq3]- anions, two Cd(qH)3]2+ cations, two ClO4- anions and two methanol molecules. |
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| Keywords: | crystal structure cadmium complex 8-quinolinol |
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