Synthesis and catalytic study of open metal site metal–organic frameworks of Cu3(BTC)2 microbelts in selective organic sulfide oxidation |
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| Authors: | Sadegh Rostamnia Rezan Rookhosh Amir Reza Abbasi |
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| Institution: | 1. Organic and Nano Group (ONG), Department of Chemistry, University of Maragheh, Maragheh, Iran;2. Faculty of Chemistry, Razi University, Kermanshah, Iran |
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| Abstract: | The synthesis of open metal site metal–organic frameworks of Cu3(BTC)2 with microbelt morphology and a study of the catalytic oxidation of organic sulfides are reported. This CuBTC was found to be an efficient, selective and waste‐free green heterogeneous co‐catalyst for the green H2O2 catalytic oxidation of sulfides. The catalyst can be isolated from the reaction mixture and reused at least five times. Copyright © 2016 John Wiley & Sons, Ltd. |
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| Keywords: | metal– organic framework open metal site MOFs microbelts (MBs) hydrogen peroxide sulfide |
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