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Study of the reaction mechanism and composition analysis of multiple-component mixed minerals DTA/T/EGD/GC on-line coupled simultaneous technique
Authors:Gencai Cai
Institution:(1) East China University of Science and Technology, 200237 Shanghai, P. R. China
Abstract:An established DTA/T/EGD/GC on-line coupled simultaneous technique and relevant equipment were applied to identify the micro impurity minerals—pyrite and siderite in two kinds of dolomite in air and N2. The proportional five-component mixed minerals (siderite, kaolinite, dolomite, calcite and quartz) and the proportional six-component mixed minerals (pyrite and the above five minerals) were detected in N2 and in air/CO2 (1∶1) separately by applying DTA/EGD/GC and DTA/GC. The experimental results provide the basis for demonstration of the reaction mechanism of thermal decomposition of various gas—solid-phase minerals in N2 and air/CO2. The compositions of six-component mixed minerals can be distinguished individually from the DTA/GC curves; reliable results are obtained.
Keywords:calcite  differential thermal analysis  dolomite  gas chromatography  kaolinite  pyrite  siderite
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