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| 含三唑基希夫碱的锰配合物的合成及结构 | |
| 引用本文： | 张引莉,范 广. 含三唑基希夫碱的锰配合物的合成及结构[J]. 无机化学学报, 2011, 27(10): 2039-2044 |
| 作者姓名： | 张引莉 范 广 |
| 作者单位： | 咸阳师范学院化学与化工学院,咸阳,712000 |
| 基金项目： | 咸阳师范学院专项科研基金(No.09XSYK215); 陕西省自然科学基础研究计划(No.2009JQ2015)资助项目 |
| 摘 要： | 合成了4-(4-氯苯基亚甲基)亚胺-1,2,4-三唑希夫碱配体(L),以及希夫碱的配合物[Mn(SO4)(H2O)2L]n,并对配合物进行了结构表征。该配合物是1个用硫酸根桥连而成的一维链状配位聚合物,相邻的链通过水分子和硫酸根的氢键相互作用形成了二维超分子结构。利用DSC技术测试了配合物和固体推进剂主要组分(HMX,NC,RDX)的二元混合体系的热分解行为。本文也对配合物做了元素,红外光谱分析。 |
| 关 键 词： | 希夫碱 结构分析 锰配合物 超分子结构 |
Syntheses and Structure Analyses of One Triazole Schiff Base Manganic Complex |
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| ZHANG Yin-Li and FAN Guang. Syntheses and Structure Analyses of One Triazole Schiff Base Manganic Complex[J]. Chinese Journal of Inorganic Chemistry, 2011, 27(10): 2039-2044 | |
| Authors: | ZHANG Yin-Li and FAN Guang |
| Affiliation: | College of Chemistry and Chemical Engineering, Xianyang Normal University, Xianyang, Shaanxi 712000, China and College of Chemistry and Chemical Engineering, Xianyang Normal University, Xianyang, Shaanxi 712000, China |
| Abstract: | A Schiff base ligand 4-(4-H-1,2,4-triazol-4-yl)-4-Cl-phenylmethanimine (L) was prepared. And complex [Mn(SO4)(H2O)2L]n with Schiff base (L) has been synthesized and structurally characterized. The complex exhibits a one-dimensional polymeric structure with sulfate bridges, and two-dimensional supramolecular network is formed through hydrogen bonding interactions between water molecules and sulfate anions. The complex and binary mixture of complex and propellant (HMX, NC, RDX) were characterized by DSC technology. In addition, elemental analysis, IR analysis are presented. CCDC: 733542. |
| Keywords: | Schiff base structural analysis manganic complex supramolecular structure |
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