| 由MCl2(M=Zn，Cd)与咪唑-4，5-二羧酸和1，4-双(咪唑-1-基)丁烷构筑的两个二重穿插二维配位聚合物的合成、结构和性质 |
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| 引用本文： | 刘宏文,卢文贯.由MCl2(M=Zn，Cd)与咪唑-4，5-二羧酸和1，4-双(咪唑-1-基)丁烷构筑的两个二重穿插二维配位聚合物的合成、结构和性质[J].无机化学学报,2011,27(9):1810-1816. |
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| 作者姓名： | 刘宏文 卢文贯 |
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| 作者单位： | 韶关学院化学系,韶关,512005 |
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| 基金项目： | 国家自然科学基金(No.21071099)资助项目 |
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| 摘 要： | 以2∶1∶4物质的量比的咪唑-4,5-二羧酸(H3IDC),1,4-双(咪唑-1-基)丁烷(bib)和ZnCl2或CdCl2为反应物,在水热条件下分别得到了1个二重穿插的二维锌(Ⅱ)配位聚合物{Zn2(IDC)(bib)Cl].H2O}n(1)和1个二重穿插的二维镉(Ⅱ)配位聚合物Cd2(HIDC)(bib)1.5Cl2]n(2)。用元素分析、红外光谱以及单晶X-射线衍射结构分析对它们的组成和结构进行了表征,并对它们的热稳定性和荧光性质进行了初步的研究。
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| 关 键 词： | 配位聚合物 晶体结构 荧光性质 |
Synthesis, Structure and Properties of Two Two-Fold Interpenetrating 2D Coordination Polymers Constructed from MCl2(M=Zn, Cd) with Imidazole-4,5-dicarboxylic Acid and 1,4-Bis(imidazol-1-yl)butane |
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| LIU Hong-Wen and LU Wen-Guan.Synthesis, Structure and Properties of Two Two-Fold Interpenetrating 2D Coordination Polymers Constructed from MCl2(M=Zn, Cd) with Imidazole-4,5-dicarboxylic Acid and 1,4-Bis(imidazol-1-yl)butane[J].Chinese Journal of Inorganic Chemistry,2011,27(9):1810-1816. |
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| Authors: | LIU Hong-Wen and LU Wen-Guan |
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| Institution: | Department of Chemistry, Shaoguan University, Shaoguan, Guangdong 512005, China and Department of Chemistry, Shaoguan University, Shaoguan, Guangdong 512005, China |
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| Abstract: | Two-fold interpenetrating 2D Zinc(Ⅱ) coordination polymer {Zn2(IDC)(bib)Cl]·H2O}n(1) and 2D cadmium(Ⅱ) coordination polymer Cd2(HIDC)(bib)1.5Cl2]n(2)(H3IDC=imidazole-4,5-dicarboxylic acid,bib=1,4-bis(imidazol-1-yl)butane) were obtained by the hydrothermal reactions of H3IDC,bib and ZnCl2 or CdCl2 with 2∶1∶4 mole ratio,respectively.Their composition and structures were determined by elemental analysis,infrared spectroscopy,and single-crystal X-ray diffraction analysis.Their thermal stabilities and luminescent properties were investigated as well. |
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| Keywords: | coordination polymer crystal structure luminescent property |
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