| 混合二烃基二氯化锡与水杨醛缩苯胺类Schiff碱1∶1配合物的合成和表征 |
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| 引用本文： | 刘宝殿,徐永祥,胡玉兰,包明. 混合二烃基二氯化锡与水杨醛缩苯胺类Schiff碱1∶1配合物的合成和表征[J]. 合成化学, 1994, 0(2) |
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| 作者姓名： | 刘宝殿 徐永祥 胡玉兰 包明 |
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| 作者单位： | 东北师范大学化学系 |
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| 摘 要： | 由混合二烃基二氯化锡（ＲＲ＇ＳｎＣｌ＿２）与水杨醛缩苯胺类Ｓｃｈｉｆｆ碱（２－ＨＯＣ＿６Ｈ＿４ＣＨ＝ＮＡｒ）反应，合成了１４种新的有机锡配合物。经元素分析、ＩＲ、ＮＭＲ和ＴＧ－ＤＳＣ测定，确定配合物的组成是有机锡与Ｓｃｈｉｆｆ碱的１：１配合物，配体以酚羟基氧原子与锡原子配位，摩尔电导率测定表明配合物均为非电解质。
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| 关 键 词： | 混合二烃基二氯化锡，Schiff碱，配合物，合成，表征 |
Synthesis and Characterization of 1 : 1 Complexes of MixedDiorganotin Dichlorides with Salicylideneanillnes |
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| Liu,Bao-Dian, Xu,Yong-Xiang, Hu,Yu-Lan,Bao,Ming. Synthesis and Characterization of 1 : 1 Complexes of MixedDiorganotin Dichlorides with Salicylideneanillnes[J]. Chinese Journal of Synthetic Chemistry, 1994, 0(2) |
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| Authors: | Liu Bao-Dian Xu Yong-Xiang Hu Yu-Lan Bao Ming |
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| Abstract: | Ccordinative reaction of EtphSnCl_2 ,BuphSnCl_2 ,EtBuSnCl_2 and BzphSnCl_2 with salicyli-deneanilines containing different subetituents in the aniline fragment have been studied. The fourteennew stoichiometry addition complexes of 1 : 1 (diorganotin dichloride : Schiff base) have been cliarac-terired by elementary analysis ,molar conductance , IR , NMR and TG-DSC. The complexes are non-electrolytes in nitrobearene. The ligands coordinate to Sn atom via phenolic O atom rather than imineN atom. |
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| Keywords: | Mixed diorsanotin dichloride Schiff base Complexes Synthesis Characterization. |
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