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| Novel Stereoselective Synthesis of （E）-β-Silylvinylstannanes via Hydromagnesiation of Silylarylacetylenes | |
| 引用本文： | 黄斌 周舟 蔡明中. Novel Stereoselective Synthesis of （E）-β-Silylvinylstannanes via Hydromagnesiation of Silylarylacetylenes[J]. 中国化学, 2006, 24(10): 1469-1471. DOI: 10.1002/cjoc.200690277 |
| 作者姓名： | 黄斌 周舟 蔡明中 |
| 作者单位： | Department of Chemistry Jiangxi Normal University，Nanchang，Jiangxi 330027，China，Department of Chemistry，Jiangxi Normal University，Nanchang，Jiangxi 330027，China，Department of Chemistry，Jiangxi Normal University，Nanchang，Jiangxi 330027，China |
| 基金项目： | Project supported by the National Natural Science Foundation of China(No.20462002)，the Natural Science Foundation of Jiangxi Province(No.0420015). |
| 摘 要： | Hydromagnesiation of silylarylacetylenes 1 in diethyl ether gave(E)-β-silylvinyl Grignard reagents 2,whichreacted with trialkylstannyl chlorides 3 to afford stereoselectively(E)-β-silylvinylstannanes 4 in good yields. |
| 关 键 词： | hydromagnesiation silylarylacetylene (E)-β-silylvinylstannane stereoselective synthesis |
| 收稿时间： | 2006-02-22 |
| 修稿时间： | 2006-02-222006-06-12 |
Novel Stereoselective Synthesis of (E)‐β‐Silylvinylstannanes via Hydromagnesiation of Silylarylacetylenes |
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| HUANG Bin, ZHOU Zhou, CAI Ming-Zhong. Novel Stereoselective Synthesis of (E)‐β‐Silylvinylstannanes via Hydromagnesiation of Silylarylacetylenes[J]. Chinese Journal of Chemistry, 2006, 24(10): 1469-1471. DOI: 10.1002/cjoc.200690277 | |
| Authors: | HUANG Bin ZHOU Zhou CAI Ming-Zhong |
| Affiliation: | Department of Chemistry, Jiangxi Normal University, Nanchang, Jiangxi 330027, China |
| Abstract: | Hydromagnesiation of silylarylacetylenes 1 in diethyl ether gave (E)‐β‐silylvinyl Grignard reagents 2 , which reacted with trialkylstannyl chlorides 3 to afford stereoselectively (E)‐β‐silylvinylstannanes 4 in good yields. |
| Keywords: | hydromagnesiation silylarylacetylene (E)‐β‐silylvinylstannane stereoselective synthesis |
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