Cerium(IV) ammonium nitrate catalyzed synthesis of α-dehydro-β-amino esters |
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| Authors: | Moumita Paira |
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| Institution: | Department of Organic Chemistry, Indian Association for the Cultivation of Science, Jadavpur, Kolkata 700 032, India |
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| Abstract: | α-Dehydro-β-amino esters have been synthesized regioselectively from acetates of Baylis-Hillman adducts with amines in the presence of a catalytic amount of ceric ammonium nitrate (CAN) in good yield. The regioselectivity does not differ with respect to the polarity of the solvent. |
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| Keywords: | Baylis-Hillman adduct Ceric ammonium nitrate Amine α-Dehydro-β-amino esters Regioselective |
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