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| 四（1-乙烯基咪唑）二异硫氰酸镉的晶体结构和电化学性能 | |
| 引用本文： | 刘光烨,陈红纳,刘法谦,李少香,李荣勋,黄素逸.四（1-乙烯基咪唑）二异硫氰酸镉的晶体结构和电化学性能[J].无机化学学报,2007,23(6):1085-1088. |
| 作者姓名： | 刘光烨 陈红纳 刘法谦 李少香 李荣勋 黄素逸 |
| 作者单位： | 1. 华中科技大学能源与动力工程学院,武汉,430074;青岛科技大学新材料研究重点实验室,青岛,266042 2. 青岛科技大学新材料研究重点实验室,青岛,266042 3. 华中科技大学能源与动力工程学院,武汉,430074 |
| 基金项目： | 国家自然科学基金;山东省自然科学基金 |
| 摘 要： | A complex Cd(NCS)2(Vim)4] (where Vim=1-vinylimidazole) was synthesized and it′s crystal structure was determined by X-ray diffraction technique. The compound crystallizes in the Monoclinic space group P21/c with the parameters: a=0.858 50(17) nm, b=0.909 90(18) nm, c=1.782 3(4) nm, β=100.14(3)°, V=1.370 5(5) nm3, Z=2. In the structure, each Cd atom is coordinated by four 1-vinylimidazole ligands and a pair of monodentate isothiocyanic groups, affording a compressed octahedral CdN6 core. The NCS- anions are trans and four N atoms from the 1-vinylimidazole ligands define the equatorial plane. From the cyclic voltammogram measurement in H2O, we know that the electrode reaction was a quasi-reversible process. CCDC: 630897. |
| 关 键 词： | 镉(II)配合物 硫氰根配合物 循环伏安 晶体结构 |
| 文章编号： | 1001-4861（2007）06-1085-04 |
| 修稿时间： | 2006-12-152007-04-17 |
Crystal and Electrochemical Property of Tetrakis(1-vinyl-1H-imidazole-kN3)diisothiocyanatocadmium(II) |
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| LIU Guang-Ye,CHEN Hong-N,LIU Fa-Qian,LI Shao-Xiang,LI Rong-Xun and HUANG Su-Yi.Crystal and Electrochemical Property of Tetrakis(1-vinyl-1H-imidazole-kN3)diisothiocyanatocadmium(II)[J].Chinese Journal of Inorganic Chemistry,2007,23(6):1085-1088. | |
| Authors: | LIU Guang-Ye CHEN Hong-N LIU Fa-Qian LI Shao-Xiang LI Rong-Xun and HUANG Su-Yi |
| Institution: | Institute of Energy and Power, Huazhong University of Science and Technology, Wuhan 430074;Key Laboratory of Advanced Materials, Qingdao University of Science and Technology, Qingdao, Shandong 266042,Key Laboratory of Advanced Materials, Qingdao University of Science and Technology, Qingdao, Shandong 266042,Key Laboratory of Advanced Materials, Qingdao University of Science and Technology, Qingdao, Shandong 266042,Key Laboratory of Advanced Materials, Qingdao University of Science and Technology, Qingdao, Shandong 266042,Key Laboratory of Advanced Materials, Qingdao University of Science and Technology, Qingdao, Shandong 266042 and Institute of Energy and Power, Huazhong University of Science and Technology, Wuhan 430074 |
| Abstract: | A complex Cd(NCS)2(Vim)4] (where Vim=1-vinylimidazole) was synthesized and it's crystal structure was determined by X-ray diffraction technique. The compound crystallizes in the Monoclinic space group P21/cwith the parameters: a=0.858 50(17) nm, b=0.909 90(18) nm, c=1.782 3(4) nm,β=100.14(3)°, V=1.370 5(5) nm3,Z=2. In the structure, each Cd atom is coordinated by four 1-vinylimidazole ligands and a pair of monodentate isothiocyanic groups, affording a compressed octahedral CdN6 core. The NCS- anions are trans and four N atoms from the 1-vinylimidazole ligands define the equatorial plane. From the cyclic voltammogram measurement in H2O, we know that the electrode reaction was a quasi-reversible process. CCDC: 630897. |
| Keywords: | cadmium(II) complex thiocyanato complex cyclic voltammetry crystal structure |
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