Efficient acyclic stereocontrol using the tethered aminohydroxylation reaction |
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| Authors: | Donohoe Timothy J Johnson Peter D Pye Richard J Keenan Martine |
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| Institution: | Department of Chemistry, University of Oxford, Chemistry Research Laboratory, Mansfield Road, Oxford OX1 3TA, UK. tiothy.donohoe@chem.ox.ac.uk |
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| Abstract: | reaction: see text] The tethered aminohydroxylation (TA) of acyclic allylic carbamates has been achieved in a stereospecific and stereoselective manner. Unusually high levels of stereocontrol were observed in the oxidation of 1,1-disubstituted substrates. |
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