| Wade规则在稠合型多面体硼烷中的应用 |
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| 引用本文： | 杨雪梅,胡培植. Wade规则在稠合型多面体硼烷中的应用[J]. 武汉大学学报(理学版), 2001, 47(6): 676-680 |
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| 作者姓名： | 杨雪梅 胡培植 |
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| 作者单位： | 武汉大学化学与分子科学学院, |
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| 摘 要： | 讨论了Wade规则经数学转换后在稠合型多面体硼烷中的应用，推广后W ade规则可以计算稠合型多面体硼烷的价成键电子对数BEP，根据稠合方式也可以计算稠合型多面体硼烷的骨架成键电子对数SEP，还可以推断某些稠合型硼烷的结构。
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| 关 键 词： | Wade规则 稠合型多面体硼烷 价成键电子对数 骨架成键电子对数 拓扑结构 分子构型 |
| 文章编号： | 0253-9888(2001)06-0676-05 |
| 修稿时间： | 2001-05-14 |
Application of the Wade Rule in Joined-type Polyhedral Boranes |
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| YANG Xue-mei,HU Pei-zhi. Application of the Wade Rule in Joined-type Polyhedral Boranes[J]. JOurnal of Wuhan University:Natural Science Edition, 2001, 47(6): 676-680 |
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| Authors: | YANG Xue-mei HU Pei-zhi |
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| Abstract: | We have discussed the application of the Wade rule which is transformed by mathematics ways in joined-type polyhedral boranes. The Wade rule transformed can calculate the number of bonding electron pairs, which is the same as those from Tang Aoqing's topological formula. If the joined way is known, the rule can calculate the number of skeleton bonding electron pairs. We can also infer the structure of some joined-type polyhedral boranes on basic of them. |
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| Keywords: | Wade rule joined-type polyhedral boranes number of bonding electron pairs number of skeleton bonding electron pairs |
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