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Synthesis,Characterization, and Crystal Structures of Various Energetic Urotropinium Salts with Azide,Nitrate, Dinitramide and Azotetrazolate Counter Ions
Authors:How‐Ghee Ang,Wolfgang Fraenk,Konstantin Karaghiosoff,Thomas M. Klapö  tke,Heinrich Nö  th,Joanna Sprott,Max Suter,Martin Vogt,Marcus Warchhold
Abstract:
Urotropinium nitrate, N‐methylurotropinium azide, dinitramide and azotetrazolate salts have been prepared and fully characterized by analytical and spectoscopic (1H, 13C, 14N NMR, IR, Raman) methods. The structures of all four compounds have been determined using X‐ray diffraction techniques and represent new examples of the class of high energy density materials (HEDMs).
Keywords:Urotropinium  N‐methylurotropinium  Azides  Nitrates  Dinitramides  Azotetrazolate salts  Crystal structure  NMR spectroscopy (multinuclear)  Vibrational spectroscopy
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