Pyramidalization of Gd3N inside a C80 cage. The synthesis and structure of Gd3N@C80 |
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| Authors: | Stevenson Steven Phillips J Paige Reid Jon E Olmstead Marilyn M Rath Sankar Prasad Balch Alan L |
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| Institution: | Department of Chemistry, University of Southern Mississippi, Hattiesburg, MS 39406-0001, USA. Steven.Stevenson@usm.edu |
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| Abstract: | The X-ray crystal structure of Gd(3)N@C(80).Ni(II)(OEP).1.5(benzene) shows that the Gd(3)N unit within the I(h) C(80) cage is pyramidal, whereas Sc(3)N@C(80), Sc(3)N@C(78), Sc(3)N@C(68), Lu(3)N@C(80) and Sc(2)ErN@C(80) have planar M(3)N units. |
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