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[{Pt_4(en)_4(NHCO~tBu)_4}{Tl(18-crown-6)}_2](PF_6)_6的合成与晶体结构(英文)
作者姓名:吾国强  陈万芝
作者单位:浙江大学化学系,浙江大学化学系 杭州310028浙江工业大学浙西分校化工系,衢州324000,杭州310028
基金项目:浙江省自然科学基金(No.Y405435)资助课题。
摘    要:The metallophilic attraction between closed shellor pseudo closed shell metal atoms with the configura-tion of d10,s2,d8has received considerable attentionrecently mainly because such metal-metal interactionsare closely associated with many important chemicaland physical properties such as catalysis,electronicconductivity and luminescence[1].The d8-d10-s2closed-shell metallophilic interactions and ligand functionali-ty have resulted in the formation and isolation ofmultinuclear aggregates with …

关 键 词:晶体结构      18-冠-6
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