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The Reaction of 4-Formylsydnone with Nitroalkanes |
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| Authors: | Wei-Jing Hung Hsien-Ju Tien Hsien-Cheng Yu |
| Abstract: | Under various basic solutions and reaction durations, 3-substituted 4-formyIsydnones and nitroalkanes containing α-active hydrogen (e.g. nitromethane and nitroethane) are converted to β-nitroalcohols, nitroalkenes and dinitroalkanes. β-Nitroalcohols are obtained only by electrochemical reaction on an electrogenerated base (EGB). The mechanism of overall reaction steps in particular is discussed. |
| Keywords: | 4-FormyIsydnone β -Nitroalcohol Nitroalkene Dinitroalkanc EGB 2-Nitro-1-[4′ -(3′ -substituted)sydnonyl]-1-hydroxylethane 2-Nitro-1-[4′ -(3′ -substituted)sydnonyl]-1-hydroxylpropane 1 3-Dinitro-2-[4′ -(3′ -substituted)sydnonyl]propane 2-Nitro-1-[4′ -(3′ -substituted)sydnonyl]ethane |